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Journal Article

Emissions Effects of Hydrogen as a Supplemental Fuel with Diesel and Biodiesel

2008-04-14
2008-01-0648
A 1.9 liter Volkswagen TDI engine has been modified to accomodate the addition of hydrogen into the intake manifold via timed port fuel injection. Engine out particulate matter and the emissions of oxides of nitrogen were investigated. Two fuels,low sulfur diesel fuel (BP50) and soy methyl ester (SME) biodiesel (B99), were tested with supplemental hydrogen fueling. Three test conditions were selected to represent a range of engine operating modes. The tests were executed at 20, 40, and 60 % rated load with a constant engine speed o 1700 RPM. At each test condition the percentage of power from hydrogen energy was varied from 0 to 40 %. This corresponds to hydrogen flow rates ranging from 7 to 85 liters per minute. Particulate matter (PM) emissions were measured using a scaning mobility particle sizer (SMPS) and a two stage micro dilution system. Oxides of nitrogen were also monitored.
Technical Paper

Comparing Measurements of Carbon in Diesel Exhaust Aerosols Using the Aethalometer, NIOSH Method 5040, and SMPS

2007-04-16
2007-01-0334
Combustion aerosols consist mainly of elemental and organic carbon (EC and OC). Since EC strongly absorbs light and thus affects atmospheric visibility and radiation balance, there is great interest in its measurement. To this end, the National Institute for Occupational Safety and Health (NIOSH) published a standard method to determine the mass of EC and OC on filter samples. Another common method of measuring carbon in aerosols is the aethalometer, which uses light extinction to measure “black carbon” or BC, which is considered to approximate EC. A third method sometimes used for estimating carbon in submicron combustion aerosols, is to measure particle size distributions using a scanning mobility particle sizer (SMPS) and calculate mass using the assumptions that the particles are spherical, carbonaceous and of known density.
Technical Paper

Significance of Fuel Sulfur Content and Dilution Conditions on Particle Emissions from a Heavily-Used Diesel Engine During Transient Operation

2007-04-16
2007-01-0319
The effects of fuel sulfur content and dilution conditions on diesel engine PM number emissions have been researched extensively through steady state testing. Most results show that the concentration of nuclei-mode particles emitted increases with fuel sulfur content. A few studies further observed that fuel sulfur content has little effect on the emissions of heavily-used engines. It has also been found that primary dilution conditions can have a large impact on the size and number distribution of the nuclei-mode particles. These effects, however, have not yet been fully understood through transient testing, the method used by governments worldwide to certify engines and regulate emissions, and a means of experimentation which generates realistic conditions of on-road vehicles by varying the load and speed of the engine.
Technical Paper

An Alternative Method for Generating Ultra-Clean Dilution Air for Engine Emissions Measurements

2007-04-16
2007-01-1111
Many engine exhaust emissions measurements require exhaust dilution. With low-emission engines, there is the possibility for contaminants in the dilution air to contribute artifacts to the emissions measurement. The objectives of this work are to discuss common methods used to clean the dilution air, to present the detailed analysis of a pressure swing adsorption (PSA) system and to compare the performance of the PSA with 2 other systems commonly used to provide dilution air for engine exhaust nanoparticle measurements. The results of the comparison are discussed in context with some emissions measurements that require exhaust dilution.
Technical Paper

Improvement of Intake Restrictor Performance for a Formula SAE Race Car through 1D & Coupled 1D/3D Analysis Methods

2006-12-05
2006-01-3654
A typical means of limiting the peak power output of race car engines is to restrict the maximum mass flow of air to the engine. The Formula SAE sanctioning body requires the use of an intake restrictor to limit performance, keep costs low, and maintain a safe racing experience. The intake restrictor poses a challenge to improving engine performance. Methods to better understand the ramifications of the restrictor on the engine lead to performance improvements that allow an edge over the competition. A one-dimensional gas exchange simulation code coupled with three-dimensional CFD is used to simulate various concepts in the improvement of restrictor performance. Ricardo's WAVE and VECTIS are the respective simulation codes. Along with this, the interaction of intake manifold and restrictor are considered. The effects of different diffuser geometries and plenum dimensions were first explored using WAVE, and then a series of different diffuser angles were simulated using WAVE-VECTIS.
Technical Paper

Dynamic Modeling of Torque-Biasing Devices for Vehicle Yaw Control

2006-02-14
2006-01-1963
This paper focuses on modeling of torque-biasing devices of a four-wheel-drive system used for improving vehicle stability and handling performance. The proposed driveline system is based on nominal front-wheel-drive operation with on-demand transfer of torque to the rear. The torque biasing components of the system are an electronically controlled center coupler and a rear electronically controlled limited slip differential. Kinematic modeling of the torque biasing devices is introduced including stage transitions during the locking stage and the unlocking/slipping stage. Analytical proofs of how torque biasing could be used to influence vehicle yaw dynamics are also included in the paper. A yaw control methodology utilizing the biasing devices is proposed. Finally, co-simulation results with Matlab®/Simulink® and CarSim® show the effectiveness of the torque biasing system in achieving yaw stability control.
Technical Paper

Effect of Local Hand Thermal Insulation on Total and Local Comfort Under Different Levels of Body Heat Deficit

2005-07-11
2005-01-2977
Introduction: There are contradictory opinions regarding the contribution of local hand thermal insulation to support local and total comfort during extravehicular activity (EVA). Instead of a local correction by means of thermal insulation on the periphery of the body to prevent heat dissipation, it may be optimal to prevent heat dissipation from the body core. To examine such a concept, the effects of different insulation levels on the left and right hands on the heat flux and temperature mosaic on the hands was measured. These variables were assessed in relation to the level of heat deficit forming in the core organs and tissues. Methods: Six subjects (4 males, 2 females) were donned in a liquid cooling/warming garment (LCWG) that totally covered the body surface except for the face. Participants wore the Phase VI space gloves including the entire micrometeoroid garment (TMG) on the left hand, and the glove without the TMG on the right hand.
Technical Paper

Improving Air Quality by Using Biodiesel in Generators

2004-10-25
2004-01-3032
A biodiesel / petroleum fuel blend and practical low-cost methods of emission control were sought to obtain reductions in emissions from diesel generators. Little direct testing of biodiesel in diesel-powered electric generators has been done. Laboratory and field evaluations were conducted to determine the influence of using biodiesel on diesel exhaust emissions. B20 (20% biodiesel / 80% petroleum diesel) was chosen because of previously successful studies with this blend level, and there is evidence that the NOx emissions increase that result from using B20 can be controlled using existing technology. B85 was selected because it is a “high blend,” which promised to give a large decrease in PM at the expense of a larger increase in NOx than B20, but still within the range of control with existing technology. Charge-air cooling and a fuel additive were tested as NOx controls. For PM, CO, and HC reduction, a diesel oxidation catalyst (DOC) was evaluated.
Technical Paper

The Influence of Engine Lubricating Oil on Diesel Nanoparticle Emissions and Kinetics of Oxidation

2003-10-27
2003-01-3179
Earlier work [1] shows that kinetics of Diesel soot oxidation is different from that of ethylene diffusion flame soot oxidation [2], possibly due to metals from lube oil. This study investigates the influence of metals on soot oxidation and the exhaust particle emissions using lube oil dosed fuel (2 % by volume). This method does not simulate normal lube oil consumption, but is used as a means of adding metals to particles for oxidation studies. This study also provides insight into the effect of systems that mix lube oil with fuel to minimize oil change service. The HTO-TDMA (High Temperature Oxidation-Tandem Differential Mobility Analyzer) technique [1] was used to measure the surface specific oxidation rate of Diesel particles over the temperature range 500-750 °C. Diesel particles sampled from the exhaust stream of a Diesel engine were size segregated by differential mobility and oxidized in situ in air in a heated flow tube of known residence time and temperature profile.
Technical Paper

Exhaust Particle Number and Size Distributions with Conventional and Fischer-Tropsch Diesel Fuels

2002-10-21
2002-01-2727
Diesel exhaust particle number concentrations and size distributions, as well as gaseous and particulate mass emissions, were measured during steady-state tests on a US heavy-duty engine and a European passenger car engine. Two fuels were compared, namely a Fischer-Tropsch diesel fuel manufactured from natural gas, and a US D2 on-highway diesel fuel. With both engines, the Fischer-Tropsch fuel showed a considerable reduction in the number of particles formed by nucleation, when compared with the D2 fuel. At most test modes, particle number emissions were dominated by nucleation mode particles. Consequently, there were generally large reductions (up to 93%) in the total particle number emissions with the Fischer-Tropsch fuel. It is thought that the most probable cause for the reduction in nucleation mode particles is the negligible sulphur content of the Fischer-Tropsch fuel. In general, there were also reductions in all the regulated emissions with the Fischer-Tropsch fuel.
Technical Paper

Single-Stage Dilution Tunnel Performance

2001-03-05
2001-01-0201
A one-stage dilution tunnel has been developed to sample and dilute diesel exhaust. The tunnel has the capability of simulating many aspects of the atmospheric dilution process. The dilution rate and overall dilution ratio, temperature, relative humidity, and residence time in the tunnel, as well as residence time and temperature in the transfer line between the tunnel and exhaust sampling point may be varied. In this work we studied the influence of the exhaust transfer line, tunnel residence time, and dilution air temperature on the exhaust particle size distribution. The influences of fuel sulfur content on the size distribution and on the sensitivity of the size distribution to dilution and sampling conditions were also examined. We do not suggest an optimum dilution scheme, but do identify critical variables.
Technical Paper

Maximal Conductive Heat Exchange through Different Body Zones in a Liquid Cooling/Warming Space Garment

2000-07-10
2000-01-2255
The maximal capability of several body areas to absorb/release heat by varying the circulating water temperature in different zones of a multi-compartment liquid cooling/warming garment (LCWG) was explored. The goal was to identify the areas that are highly effective to stabilize body comfort, and to use this information for developing a more physiologically-based design of the space suit. The results showed a high capability of the upper compared to the lower body in the conductive heat exchange process. The involvement of the head in this process is still problematic, because there was not a high level of direct heat absorption/release through the cooling/warming hood in the LCWG. Exclusion of the legs but with involvement of the feet in heat exchange had no effect on comfort of the distal parts of the extremities and core body status.
Technical Paper

Influence of Fuel Additives and Dilution Conditions on the Formation and Emission of Exhaust Particulate Matter from a Direct Injection Spark Ignition Engine

2000-06-19
2000-01-2018
Experiments were performed to measure the number-weighted particle size distributions emitted from a gasoline direct injection (GDI) engine. Measurements were made on a late model vehicle equipped with a direct injection spark ignition engine. The vehicle was placed on a chassis dynamometer, which was used to load the engine to road load at five different vehicle speeds ranging from 15 - 100 km/hr. Dilution of the exhaust aerosol was carried out using a two-stage dilution system in which the first stage dilution occurs as a free jet. Particle size distributions were measured using a TSI 3934 scanning mobility particle sizer. Generally speaking, the presence of the additives did not have a strong, consistent influence on the particle emissions from this engine. The polyether amine demonstrated a reduction in particle number concentration as compared to unadditized base fuel.
Technical Paper

Nanoparticle Growth During Dilution and Cooling of Diesel Exhaust: Experimental Investigation and Theoretical Assessment

2000-03-06
2000-01-0515
Nanoparticle formation during exhaust sampling and dilution has been examined using a two-stage micro-dilution system to sample the exhaust from a modern, medium-duty diesel engine. Growth rates of nanoparticles at different exhaust dilution ratios and temperatures have been determined by monitoring the evolution of particle size distributions in the first stage of the dilution system. Two methods, graphical and analytical, are described to determine particle growth rate. Extrapolation of size distribution down to 1 nm in diameter has been demonstrated using the graphical method. The average growth rate of nanoparticles is calculated using the analytical method. The growth rate ranges from 6 nm/sec to 24 nm/sec, except at a dilution ratio of 40 and primary dilution temperature of 48 °C where the growth rate drops to 2 nm /sec. This condition seems to represent a threshold for growth. Observed nucleation and growth patterns are consistent with predictions of a simple physical model.
Technical Paper

Exhaust Particulate Emissions from a Direct Injection Spark Ignition Engine

1999-03-01
1999-01-1145
Experiments were performed to measure the average and time-resolved particle number emissions and number-weighted particle size distributions from a gasoline direct injection (GDI) engine. Measurements were made on a late model vehicle equipped with a direct injection spark ignition engine. The vehicle was placed on a chassis dynamometer, which was used to load the engine to road load at five different vehicle speeds ranging from 13 - 90 km/hr. Particle number emissions were measured using a TSI 3020 condensation nucleus counter, and size distributions were measured using a TSI 3934 scanning mobility particle sizer. Average polydisperse number concentration was found to increase from 1.1 × 108 particles/cm3 at 13 km/hr to 2.8 × 108 particles/cm3 at 70 km/hr. Under a closed-loop, stoichiometric homogeneous charge operating mode at 90 km/hr, number emissions fell to 9.3 × 107 particles/cm3 (at all other operating conditions, the engine was in a lean stratified charge operating mode).
Technical Paper

The Influence of Dilution Conditions on Diesel Exhaust Particle Size Distribution Measurements

1999-03-01
1999-01-1142
Particle size distribution and number concentration measurements have been made in the diluted exhaust of a medium-duty, turbocharged, aftercooled, direct-injection Diesel engine using a unique variable residence time micro-dilution system that allows systematic variation of dilution and sampling conditions, and a scanning mobility particle sizer (SMPS). The measurements show that the number concentrations in the nanoparticle (Dp < 50 nm) and the ultrafine (Dp < 100 nm) ranges are very sensitive to dilution conditions and fuel sulfur content. Changes in concentration of up to two orders of magnitude have been observed when conditions are varied over the range that might be encountered in typical laboratory dilution systems. For example, at a dilution ratio of 12, dilution temperature of 32 °C, and a residence time of 1000 ms, the number concentrations reach 6 × 108 part.
Technical Paper

Diesel Trap Performance: Particle Size Measurements and Trends

1998-10-19
982599
Particle concentrations and size distributions were measured in the exhaust of a turbocharged, aftercooled, direct-injection, Diesel engine equipped with a ceramic filter (trap). Measurements were performed both upstream and downstream of the filter using a two-stage, variable residence time, micro-dilution system, a condensation particle counter and a scanning mobility particle sizer set up to count and size particles in the 7-320 nm diameter range. Engine operating conditions of the ISO 11 Mode test were used. The engine out (upstream of filter) size distribution has a bimodal, log normal structure, consisting of a nuclei mode with a geometric number mean diameter, DGN, in the 10-30 nm range and an accumulation mode with DGN in the 50-80 nm range. The modal structure of the size distribution is less distinct downstream of the filter. Nearly all the particle number emissions come from the nuclei mode, are nanoparticles (Dp < 50nm), and are volatile.
Technical Paper

Characterization of Exhaust Particulate Emissions from a Spark Ignition Engine

1998-02-23
980528
Exhaust particulate emissions from a 4-cylinder, 2.25 liter spark ignition engine were measured and characterized. A single-stage ejector-diluter system was used to dilute and cool the exhaust sample for measurement. The particulate measurement equipment included a condensation nucleus counter and a scanning mobility particle sizer. Exhaust measurements were made both upstream and downstream of the catalytic converter using three different fuels. Unlike particulate emissions in diesel engines, spark ignition exhaust particle emissions were found to be highly unstable. Typically, a stable “baseline” concentration on the order of 105 particles/cm3 is emitted. Occasionally, however, a “spike” in the exhaust particle concentration is observed. The exhaust particle concentrations observed during these spikes can increase by as much as two orders of magnitude over the baseline concentration.
Technical Paper

Diesel Exhaust Particle Size: Measurement Issues and Trends

1998-02-23
980525
Exhaust particle number concentrations and size distributions were measured from the exhaust of a 1995 direct injection, Diesel engine. Number concentrations ranged from 1 to 7.5×107 particles/cm3. The number size distributions were bimodal and log-normal in form with a nuclei mode in the 7-15 nm diameter range and an accumulation mode in the 30-40 nm range. For nearly all operating conditions, more than 50% of the particle number, but less than 1% of the particle mass were found in the nuclei mode. Preliminary indications are that the nuclei mode particles are solid and formed from volatilization and subsequent nucleation of metallic ash from lubricating oil additives. Modern low emission engines produce low concentrations of soot agglomerates. The absence of these agglomerates to act as sites for adsorption or condensation of volatile materials makes nucleation and high number emissions more likely.
Technical Paper

Influence of an Iron Fuel Additive on Diesel Combustion

1998-02-23
980536
This program used a 0.6 liter DI NA single cylinder diesel engine to study the influence of ferrocene as a fuel additive on particulate and NOx emissions and heat release rates. Previous Studies1,15 have shown efficiency and particulate emission benefits only after engine conditioning. Two engine configurations were tested: standard aluminum piston with normal engine deposits and a second test with the engine cleaned to “new engine condition”, but with the piston replaced with a thermal barrier coated piston. Particle concentration and size in roughly the 7.5 to 750 nm diameter range were measured with a condensation nucleus counter and an electrical aerosol analyzer. Heat release rates and IMEPs were calculated from in-cylinder pressure data. Particle number concentrations increased substantially when the 250 ppm dose was first started with both engine configuration, but decreased 30% to 50% with conditioning.
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